Purification - Crystallization, sublimation, distillation, differential extraction, and chromatography - principles and their applications.
Qualitative analysis - Detection of nitrogen, sulphur, phosphorus, and halogens.
Quantitative analysis (basic principles only) - Estimation of carbon, hydrogen, nitrogen, halogens, sulphur, phosphorus.
Calculations of empirical formulae and molecular formulae: Numerical problems in organic quantitative analysis,
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Tetravalency of carbon: Shapes of simple molecules - hybridization (s and p): Classification of organic compounds based on functional groups: and those containing halogens, oxygen, nitrogen, and sulphur; Homologous series: Isomerism - structural and stereoisomerism.
Nomenclature (Trivial and IUPAC)
Covalent bond fission - Homolytic and heterolytic: free radicals, carbocations, and carbanions; stability of carbocations and free radicals, electrophiles, and nucleophiles.
Electronic displacement in a covalent bond
- Inductive effect, electromeric effect, resonance, and hyperconjugation.
Common types of organic reactions- Substitution, addition, elimination, and rearrangement.
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Classification, isomerism, IUPAC nomenclature, general methods of preparation, properties, and reactions.
Alkanes - Conformations: Sawhorse and Newman projections (of ethane): Mechanism of halogenation of alkanes.
Alkenes - Geometrical isomerism: Mechanism of electrophilic addition: addition of hydrogen, halogens, water, hydrogen halides (Markownikoffs and peroxide effect): Ozonolysis and polymerization.
Alkynes - Acidic character: Addition of hydrogen, halogens, water, and hydrogen halides: Polymerization.
Aromatic hydrocarbons - Nomenclature, benzene - structure and aromaticity: Mechanism of electrophilic substitution: halogenation, nitration.
Friedel - Craft's alkylation and acylation, directive influence of the functional group in mono- substituted benzene.
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General methods of preparation, properties, and reactions; Nature of C-X bond; Mechanisms of substitution reactions.
Uses; Environmental effects of chloroform, iodoform freons, and DDT.
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General methods of preparation, properties, reactions, and uses.
ALCOHOLS, PHENOLS, AND ETHERS
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Alcohols: Identification of primary, secondary, and tertiary alcohols: mechanism of dehydration.
Phenols: Acidic nature, electrophilic substitution reactions: halogenation. nitration and sulphonation. Reimer - Tiemann reaction.
Ethers: Structure.
Aldehyde and Ketones: Nature of carbonyl group; Nucleophilic addition to >C=O group, relative reactivities of aldehydes and ketones; Important reactions such as - Nucleophilic addition reactions (addition of HCN. NH3, and its derivatives), Grignard reagent; oxidation: reduction (Wolf Kishner and Clemmensen); the acidity of -hydrogen. aldol condensation, Cannizzaro reaction. Haloform reaction, Chemical tests to distinguish between aldehydes and Ketones.
Carboxylic Acids
Acidic strength and factors affecting it,
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General methods of preparation. Properties, reactions, and uses.
Amines: Nomenclature, classification structure, basic character, and identification of primary, secondary, and tertiary amines and their basic character.
Diazonium Salts: Importance in synthetic organic chemistry.
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General introduction and importance of biomolecules.
CARBOHYDRATES - Classification; aldoses and ketoses: monosaccharides (glucose and fructose) and constituent monosaccharides of oligosaccharides (sucrose, lactose, and maltose).
PROTEINS - Elementary Idea of -amino acids, peptide bond, polypeptides. Proteins: primary, secondary, tertiary, and quaternary structure (qualitative idea only), denaturation of proteins, enzymes.
VITAMINS – Classification and functions.
NUCLEIC ACIDS – Chemical constitution of DNA and RNA. Biological functions of nucleic acids.
Hormones (General introduction)
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Detection of extra elements (Nitrogen, Sulphur, halogens) in organic compounds; Detection of the following functional groups; hydroxyl (alcoholic and phenolic), carbonyl (aldehyde and ketones) carboxyl, and amino groups in organic compounds.
The chemistry involved in the preparation of the following: Inorganic compounds; Mohr’s salt, potash alum.
Organic compounds: Acetanilide, p-nitro acetanilide, aniline yellow, iodoform.
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The chemistry involved in the titrimetric exercises – Acids, bases and the use of indicators, oxalic- acid vs KMnO4, Mohr’s salt vs KMnO4
Chemical principles involved in the qualitative salt analysis: Cations – Pb2+, Cu2+, Al3+, Fe3+, Zn2+, Ni2+, Ca2+, Ba2+, Mg2+, NH+
Anions- CO2−, S2-,SO2−, NO3-, NO2-, Cl-, Br-, I- ( Insoluble salts excluded).
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Chemical principles involved in the following experiments:
1. Enthalpy of solution of CuSO4
2. Enthalpy of neutralization of strong acid and strong base.
3. Preparation of lyophilic and lyophobic sols.
4. Kinetic study of the reaction of iodide ions with hydrogen peroxide at room temperature.
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